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Shape Memory Alloy

Materials Engineering

A shape-memory alloy is a metal that can be bent or deformed while cold and then made to spring back to an earlier, remembered shape simply by heating it, a property that comes from a reversible change between two crystal structures: a lower-temperature martensite phase, which deforms easily by rearranging its crystal twins rather than breaking atomic bonds, and a higher-temperature austenite phase, which the metal returns to on heating, pulling the deformed shape back with it. Shape-memory behavior in various alloys was observed as early as the 1930s and 1940s, but the alloy that made the effect practically useful, a nickel-titanium compound later marketed as Nitinol, was developed at the United States Naval Ordnance Laboratory in 1962 and 1963; according to the standard account, its shape-memory property was discovered by accident when a researcher held a lighter under a bent sample during a meeting and watched it straighten back out as it warmed. Nitinol and related shape-memory alloys are now used in applications including dental braces, medical stents, aircraft components and seismic bracing for buildings.

Facts
Patent or First-Use Date
1965-03-23 1
YearSourced to the subject's own account
1962 2
SignificanceSourced to the subject's own account
Nitinol's shape-memory effect was dramatically demonstrated when a folded, accordion-like sample was passed around a 1961 laboratory management meeting and flexed by participants, the moment credited with making the effect practically recognized. 2
FAQs

How was the shape-memory effect of Nitinol first shown to its developers

A meeting demonstration in 1961: a folded sample straightened back out when a participant warmed it with a pipe lighter.

It was shown to a room of people. In 1961 researchers at the United States Naval Ordnance Laboratory presented a sample of the nickel-titanium alloy at a laboratory management meeting. The sample was folded up like an accordion and passed around, and the participants flexed it. One of them held the heat of a pipe lighter to the strip, and it contracted and took back its earlier shape. A year later the laboratory announced that it had successfully created Nitinol.
Connections

Associated With

Nickel, Materials
Nitinol, Materials

Nitinol, a nickel-titanium alloy, is the best known shape-memory alloy.

In Field

Source Shape-memory alloy (Wikipedia)
Sources
1. US Patent 3174851A, Nickel-base alloys
Abstract, opening sentence; publication date field shows 1965-03-23
Quote, Abstract, opening sentence; publication date field shows 1965-03-23
This invention relates to a series of novel structural alloys of the intermetallic compound type which are characterized by unusual mechanical and physical properties.
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2. Nitinol (Wikipedia)
Wikipedia
  • History section, NOL announcement sentence
    One year later, the Naval Ordinance Lab announced the successful creation of nitinol.
  • History section, 1961 demonstration sentence
    In 1961, they presented a sample at a laboratory management meeting. The sample, folded up like an accordion, was passed around and flexed by the participants.
View the Source
Shape-memory alloy (Wikipedia)
In Field: Materials Engineering, Introduction
Quote, In Field: Materials Engineering, Introduction
In metallurgy, a shape-memory alloy (SMA) is an alloy that can be deformed when cold but returns to its pre-deformed ("remembered") shape when heated.
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