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Mercerization

Textile Engineering

Mercerization is a chemical finishing treatment applied mainly to cotton and flax fabric or yarn, most often by soaking it in a 20 to 26 percent solution of sodium hydroxide before thoroughly washing it out, which increases the fiber's strength, improves how readily it takes up dye and reduces later shrinkage. The English scientist John Mercer created the treatment in 1844, and of the effects he observed he considered the improved dye uptake the most technically important, though he also experimented separately with sulfuric acid and zinc chloride, discovering what became known as the parchmentizing effect. The glossy, silk-like sheen now most associated with mercerized cotton was not part of Mercer's original process; Horace Lowe discovered in 1889 that holding the fabric under tension during the treatment, which straightens the fiber's cross-section toward circular, produces that characteristic luster.

Facts
Year
1844 1
Significance
Improves dye uptake and tear strength, reduces shrinkage, and imparts a silk-like luster 1
FAQs

Why is the fabric washed after it is treated with sodium hydroxide in mercerization?

Washing out the alkali turns alkali cellulose into cellulose hydrate.

The washing completes the chemical change in the fiber. The sodium hydroxide destroys the natural spiral form of the cellulose and forms a substance called alkali cellulose. Washing out the alkali then changes that alkali cellulose into cellulose hydrate, which is the form the finished fiber keeps.
Connections

Associated With

John Mercer, Engineers
Source John Mercer (Grace's Guide)

In Field

Source Mercerisation (Wikipedia)

Invented By

John Mercer, Engineers
Source John Mercer (Grace's Guide)
Sources
1. Mercerisation (Wikipedia)
  • Development
    The process was devised in 1844 by John Mercer
  • Overview, effects
    improves dye uptake and tear strength, reduces fabric shrinkage, and imparts a silk-like luster.
  • In Group: Textile Finishing Machinery and Processes, Development: The process was devised in 1844 by John Mercer
  • In Field: Textile Engineering, Categories
    Textile treatments
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John Mercer (Grace's Guide)
  • Associated With: John Mercer, Notes
    Prior to the introduction of the Mill engraving machine and the present methods of producing rainbow, or ombre effects, these were obtained by means of the ribbon roller, the invention of John Mercer, a pioneer in the calico-printing industry, whose name is a household one as the inventor of the process of mercerising cotton cloth.
  • Invented By: John Mercer, Notes
    Prior to the introduction of the Mill engraving machine and the present methods of producing rainbow, or ombre effects, these were obtained by means of the ribbon roller, the invention of John Mercer, a pioneer in the calico-printing industry, whose name is a household one as the inventor of the process of mercerising cotton cloth.
View the Source
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