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Electrolysis

Chemical Engineering

Electrolysis is a chemical process that uses a direct electric current passed through an electrolyte, a substance containing free-moving ions, to drive a chemical reaction that would not occur on its own, separating a compound into its constituent elements at two electrodes connected to an external power source. The English scientists William Nicholson and Anthony Carlisle carried out the first sustained electrolysis in 1800, splitting water into hydrogen and oxygen using a voltaic pile, and Humphry Davy used electrolysis between 1807 and 1808 to discover the elements potassium, sodium, barium, calcium, and magnesium; Michael Faraday coined the term electrolysis itself in 1834. The technique became industrially transformative with the 1886 development of the Hall-Heroult process for producing aluminum by electrolysis, which cut the metal's price from roughly four dollars to thirty cents a pound, and electrolysis remains central to metal refining and the industrial production of many chemical compounds.

Facts
Patent or First-Use Date
1886-07-09 1
Year
1800 2
Significance
The Hall-Heroult process, an industrial application of electrolysis patented in 1886, cut the price of aluminum from about four dollars to thirty cents a pound, transforming aluminum from a rare metal into a widely used industrial material. 2
FAQs

Why did electrolysis make aluminum so much cheaper?

The 1886 Hall-Heroult process cut aluminum from about four dollars to thirty cents a pound.

Aluminum was hard to produce until the Hall-Heroult process applied electrolysis to it, with a patent application filed on 9 July 1886. Aluminum's price then dropped from four dollars to thirty cents per pound, which benefited many industries.
Connections

Associated With

Aluminum, Materials
Source Humphry Davy (New World Encyclopedia)

In Field

Source Electrolysis, Wikipedia
Sources
1. US Patent 400664, Process of reducing aluminium from its fluoride salts by electrolysis, Google Patents
Patent header, application filing line
Quote, Patent header, application filing line
Original application filed July 9, 1886, Serial No. 207,601.
View the Source
2. Electrolysis, Wikipedia
  • History, Timeline section, 1800 entry
    1800, William Nicholson and Anthony Carlisle (and also Johann Ritter), demonstrated the first sustained electrolysis of water into hydrogen and oxygen using a voltaic pile.
  • History section, Hall-Heroult paragraph
    This became known as the Hall-Heroult process, which benefited many industries because aluminum's price then dropped from four dollars to thirty cents per pound.
  • In Field: Chemical Engineering, Categories
    Chemical processes
  • In Group: Electrochemical Cells and Processes, Lead paragraph
    is a technique that uses direct electric current (DC) to drive an otherwise non-spontaneous
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Humphry Davy (New World Encyclopedia)
Associated With: Humphry Davy, Infobox, Known for
Quote, Associated With: Humphry Davy, Infobox, Known for
Electrolysis, Chlorine, Davy lamp
View the Source
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