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Titanium

ty-TAY-nee-um
Also Known As Ti IUPAC chemical symbol, used as the common short form in engineering and materials contexts.
Aerospace Engineering

Titanium was identified as a distinct element in 1791 by the English clergyman and mineralogist William Gregor, examining a black sand from Cornwall, but it took until 1910 for anyone to isolate a reasonably pure sample and until 1940, when the Luxembourg-born metallurgist William Justin Kroll developed a practical reduction process, for the metal to become available in any industrial quantity, so despite being the ninth most abundant element in the crust it remained a laboratory curiosity for a century and a half. The Kroll process, still the dominant production method, reduces titanium tetrachloride with magnesium in an inert atmosphere because molten titanium reacts violently with oxygen, nitrogen and carbon, which is also why the metal is difficult and costly to work compared with steel or aluminum. What that cost buys is a strength-to-weight ratio matching many steels at roughly half the density, exceptional corrosion resistance from a tenacious oxide film, and biocompatibility that makes it the standard material for surgical implants.

Facts
Primary Use
Aerospace airframes and engine components, and surgical implants, chosen for strength-to-weight ratio, corrosion resistance and, for implants, biocompatibility. 2
Origin Year
1791 1
The English clergyman and mineralogist William Gregor identified titanium as a distinct element in 1791.
Classification
Material Class
Metal 1
Learn More
Gregor's Black Sand and a Century of Failure

This article records tradition as it has been passed down and reported. Its sources are not yet part of the atlas's verified catalogue.

Titanium is the ninth most abundant element in the Earth's crust, which makes its long absence from industry one of metallurgy's stranger stories. William Gregor, an English clergyman and amateur mineralogist, identified it as a distinct element in 1791 while examining a black sand from a valley in Cornwall, but identifying an element and producing it are different achievements: nobody managed to isolate a reasonably pure sample of titanium until 1910, and even then it stayed a laboratory curiosity for another three decades, too difficult to reduce from its ore in any useful quantity. The gap between 1791 and 1940 is not a story of neglect. Molten titanium reacts violently with oxygen, nitrogen and carbon, which meant every early attempt at extracting it from ore also contaminated it, producing a brittle metal with none of the properties that make titanium valuable today. An element that had been sitting in plain sight, chemically identified for a century and a half, still needed someone to solve a purely practical problem before it could become a metal anyone could build with.

The Kroll Process and the Metal That Took Flight

This article records tradition as it has been passed down and reported. Its sources are not yet part of the atlas's verified catalogue.

William Justin Kroll, a Luxembourg-born metallurgist, solved titanium's century and a half old production problem in 1940 with a process that still bears his name and still dominates titanium production today. The Kroll process reduces titanium tetrachloride with magnesium inside an inert atmosphere, keeping the molten metal away from the oxygen, nitrogen and carbon it reacts with so violently, and that inert-atmosphere requirement is exactly why titanium remains difficult and costly to work compared with steel or aluminum even now. What that cost buys is a short list of properties nothing else quite matches at once: a strength-to-weight ratio that equals many steels at roughly half the density, a tenacious oxide film that gives it exceptional corrosion resistance, and a biocompatibility that makes it the standard material for surgical implants. Aerospace and biomedical engineering ended up sharing the same metal for almost opposite reasons, one needing strength without weight thirty thousand feet up and the other needing a material the human body will not reject, and both are still paying the Kroll process's own production cost for the privilege.

Connections

Associated With

Biomedical Engineering, Fields

Titanium's biocompatibility and corrosion resistance make it a standard material for surgical implants and prosthetics.

Source Technology: A World HistoryDaniel R. Headrick
Dental Implant, Inventions

Titanium is the standard dental implant material because it bonds with bone.

Forging, Methods
Machining, Methods
Nitinol, Materials
Nitinol, Materials

Nitinol is a nickel-titanium alloy

Pacemaker, Inventions
The Jet Engine, Inventions

Titanium alloys are used throughout jet engine compressor sections for their strength to weight ratio at high temperature.

Source Technology: A World HistoryDaniel R. Headrick
Titanium Alloy, Materials

Titanium alloys are based on titanium

Total Hip Replacement, Inventions

Titanium alloys are used for hip replacement stems and cups.

Welding, Methods

In Field

Source Encyclopaedia BritannicaEncyclopaedia Britannica editors

Long-Form Articles

In the Other Atlases
Sources
1. A History of Technology
Charles Singer, E. J. Holmyard, A. R. Hall and Trevor I. Williams, editors, Oxford University Press, 1954material-class sentence
Quote, material-class sentence
The Kroll process, still the dominant production method, reduces titanium tetrachloride with magnesium in an inert atmosphere because molten titanium reacts violently with oxygen, nitrogen and carbon, which is also why the metal is difficult and costly to work compared with steel or aluminum.
View the Source
2. Technology: A World History
Daniel R. Headrick, Oxford University Press, 2009View the Source
Titanium (Wikipedia)
Wikipedia contributors, Wikimedia Foundation
  • Introduction
    Titanium is a chemical element; it has symbol Ti and atomic number 22, a lustrous transition metal with a silver color, low density, and high strength.
  • Applications
    Titanium alloys are strong, lightweight, and versatile, with applications including aerospace (jet engines, missiles, and spacecraft).
View the Source
Encyclopaedia Britannica
Encyclopaedia Britannica editors, Encyclopaedia Britannica, Inc.In Field: Aerospace EngineeringView the Source
Frequently Asked Questions

Who discovered titanium, and where does its name come from?

William Gregor identified it in 1791; Martin Heinrich Klaproth independently rediscovered and named it, after the Titans, in 1795.

The English clergyman and mineralogist William Gregor identified titanium as a distinct element in 1791, working from a black sand he found in Cornwall. Four years later, in 1795, the Prussian chemist Martin Heinrich Klaproth independently rediscovered the same element in the mineral rutile and gave it the name it carries today, after the Titans of Greek mythology. Gregor is credited with the original discovery and Klaproth with the name; neither man could isolate the pure metal, which did not happen until 1910, and titanium had no real industrial production until William Justin Kroll practical reduction process of 1940.

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