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Silicon

Also Known As Si IUPAC chemical symbol; used as the common short form in engineering and materials contexts.
Electrical Engineering

Silicon is a chemical element and semiconductor, the second most abundant element in the Earth crust, whose electrical conductivity can be precisely controlled by introducing trace impurities in a process called doping. Purified to extreme levels and grown into single crystal ingots, it is the base material of nearly every transistor and integrated circuit manufactured since the 1960s, and gave Silicon Valley its name.

Facts
Primary Use
The base semiconductor material for transistors, integrated circuits and solar photovoltaic cells. 1
Origin Year
1824 2
Jons Jacob Berzelius first isolated pure silicon in 1824.
Classification
Material Class
Semiconductor 1
Learn More
The Element Everyone Was Standing On

This article records tradition as it has been passed down and reported. Its sources are not yet part of the atlas's verified catalogue.

Silicon is the second most abundant element in the Earth's crust, present in ordinary sand and rock everywhere, which makes it an odd choice at first glance for the material every modern computer is built from. What makes silicon useful is not its abundance but a property abundance had nothing to do with: its electrical conductivity can be precisely controlled by introducing trace impurities in a process called doping, turning an otherwise unremarkable element into a switch that can be built, by the billion, onto a single chip. Purified to extreme levels and grown into single crystal ingots, doped silicon became the base material of nearly every transistor and integrated circuit manufactured since the 1960s, common enough and central enough to the industry that it gave an entire region of California its name. The element had been sitting underfoot the whole time; what changed was the discovery that it could be made to behave like a semiconductor on command.

Berzelius and the Element That Waited to Be Purified

This article records tradition as it has been passed down and reported. Its sources are not yet part of the atlas's verified catalogue.

The Swedish chemist Jons Jacob Berzelius first isolated pure silicon in 1824, more than a century before the element would become the physical foundation of the computer industry. Berzelius could not have known what silicon would become; in his own time, isolating a new element in pure form was the achievement itself, part of a broader project of chemistry sorting out what the material world was actually made of. Silicon's real significance was invisible to nineteenth century chemistry and had to wait for twentieth century physics: only once researchers understood that a doped crystal of the element could act as a controllable semiconductor did Berzelius's purified sample become the ancestor of every silicon wafer since. It is a common enough pattern in the history of materials, an element or compound identified and purified for reasons that have nothing to do with the use eventually found for it, and silicon is one of the starkest examples, since almost nothing about isolating a pure sample in 1824 suggested it would end up inside every computer built two centuries later.

Connections

Associated With

Source Chemical vapor deposition (Wikipedia)Wikipedia contributors
Chemical Vapor Deposition, Methods

Chemical vapor deposition lays down silicon and silicon compound films in chip fabrication.

Diode, Inventions

Silicon is the semiconductor material of the common junction diode

Flash Memory, Inventions

Flash memory is fabricated on silicon wafers.

Gallium Arsenide, Materials

Gallium arsenide and silicon are the two principal semiconductor materials in electronics

Gallium Nitride, Materials

GaN devices are grown on silicon substrates and compete with silicon power devices

Nanotechnology, Fields

Semiconductor nanofabrication of silicon devices is one of the field's founding applications.

Nanotechnology, Fields
Photolithography, Methods

Photolithography patterns circuits onto silicon wafers.

Semiconductor Doping, Methods

Doping introduces impurities into silicon to set its electrical conductivity type.

Silicon carbide is a wide-bandgap semiconductor increasingly used alongside and in place of silicon in power electronics, where it tolerates higher voltages, temperatures and switching frequencies.

Solar Cell, Inventions

Crystalline silicon is the dominant photovoltaic material in solar cells.

Source Technology: A World HistoryDaniel R. Headrick
Source Technology: A World HistoryDaniel R. Headrick
Transistor, Inventions
Wafer Dicing, Methods
Source Die singulation (Wikipedia)Wikipedia contributors
Wafer Dicing, Methods

Wafer dicing cuts a processed silicon wafer into individual chips.

Wire Bonding, Methods

In Field

Source Technology: A World HistoryDaniel R. Headrick

Long-Form Articles

In the Other Atlases
Sources
1. Technology: A World History
Daniel R. Headrick, Oxford University Press, 2009
  • material-class sentence
    Silicon is a chemical element and semiconductor, the second most abundant element in the Earth crust, whose electrical conductivity can be precisely controlled by introducing trace impurities in a process called doping.
  • In Field: Electrical Engineering
  • Associated With: The Integrated Circuit
  • Associated With: The Transistor
View the Source
2. A History of Technology
Charles Singer, E. J. Holmyard, A. R. Hall and Trevor I. Williams, editors, Oxford University Press, 1954View the Source
Silicon (Wikipedia)
Wikipedia contributors, Wikimedia Foundation
  • Introduction
    Silicon is a chemical element; it has symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic lustre.
  • Silicon semiconductors
    In 1959, Robert Noyce developed the first silicon-based integrated circuit at Fairchild Semiconductor.
View the Source
Die singulation (Wikipedia)
Wikipedia contributors, Wikimedia FoundationAssociated With: Wafer Dicing, Introduction
Quote, Associated With: Wafer Dicing, Introduction
Materials diced include glass, alumina, silicon, gallium arsenide (GaAs), silicon on sapphire (SoS), ceramics, and delicate compound semiconductors.
View the Source
Chemical vapor deposition (Wikipedia)
Wikipedia contributors, Wikimedia FoundationAssociated With: Chemical Vapor Deposition, Introduction
Quote, Associated With: Chemical Vapor Deposition, Introduction
These materials include: silicon (dioxide, carbide, nitride, oxynitride), carbon (fiber, nanofibers, nanotubes, diamond and graphene), fluorocarbons, filaments, tungsten, titanium nitride and various high-κ dielectrics.
View the Source

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